By Derek H. R. Barton, Donald T. Sawyer (auth.), Derek H. R. Barton, Arthur E. Martell, Donald T. Sawyer (eds.)
ISBN-10: 1461363071
ISBN-13: 9781461363071
ISBN-10: 1461530008
ISBN-13: 9781461530008
This monograph involves the complaints of the 5th overseas Symposium at the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in collage Station, Texas, March 14-19, 1993. It comprises an introductory bankruptcy authored via Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing displays via the plenary teachers and invited audio system. one of many invited audio system, who couldn't publish a manuscript for purposes past his keep an eye on, is represented through an summary of his lecture. additionally integrated are abstracts of forty-seven posters contributed via contributors within the symposium. Readers who may need to understand extra concerning the topics awarded in summary shape are invited to speak without delay with the authors of the abstracts. this can be the 5th foreign symposium that has been hung on this topic. the 1st used to be hosted through the CNRS, might 21-29, 1979, in Bendor, France (on the Island of Bandol). the second one assembly was once geared up as a NATO workshop in Padova, Italy, June 24-27, 1984. This was once via a gathering in Tsukuba, Japan, July 12-16, 1987. The fourth symposium used to be held at Balatonfured, Hungary, September 10-14, 1990. The 6th assembly is scheduled to ensue in Delft, The Netherlands (late Spring, 1996); the organizer and host might be Professor R. A. Sheldon.
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Additional resources for The Activation of Dioxygen and Homogeneous Catalytic Oxidation
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Drajo [24], in contrast, favors the addition of LCoIIIOOH, formed by reaction of Co with 02 and a proton, to the olefin. Whichever mechanism [27] is correct, one thing is clear: non-classical oxidation of olefins is observed only in the presence of a coreductant. Nishinaga - H m LC~O '-SPh H -PhCHO - I LCo H PhCH=CH2 - I LCo H-CHPh I CHs O2 - - m LCo-O-O-CHPh I CHs Drago m LCo -OOH RCH=CHa - H+ RCHCHs I 0 RCH(02H)CHs products Co - '0"""- CoL m - RCOCHs + RCH(OH)CHs Figure 7. Mechanism of cobalt Schiff base catalyzed co-oxidation of alcohols and terminal oletins.
H. Mimoun, in: "Comprehensive Coordination Chemistry", Vol. 6, G. Wilkinson, RD. , Pergamon, Oxford, 1987, pp. 317-410. 12. P. W. van Krevelen, Chern. Eng. , Spec. Suppl. 3:41-57 (1954). 13. For reviews see: L. Vaska, Acc. Chern. Res. S. Valentine, Chern. Rev. C. H. Timmons and AE. Martell, Chern. Rev. 84:137-203 (1984). 14. P. Collman, M. W. Hosking, 1. Arn. Chern. Soc. 89:4809 (1967). 15. W. Stern,1. Chern. , Chern. Cornrnun. 736 (1970). 16. H. Kropf and K. Knaak, Tetrahedron 28:1143 (1972) and references cited therein.
E. Hamilton, RS. Drago and A Zombek, 1. Am. Chern. Soc. 109:374 (1987). 25. A Nishinaga, Tetrahedron Lett. 29:6309 (1988). 26. For an excellent recent review see R Drago, Coord. Chern. Rev. 117:185-213 (1992). 27. M. Pizzotti, S. Cenini and G. La Monica, Inorg. Chirn. Acta 33:161 (1978). 28. M. J. Geursen, Reel. Trav. Chirn. Pays-Bas 86:520 (1967). 28 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. A Nishinaga and H. Tomita,! Mol. Catal. 7:179 (1980).
The Activation of Dioxygen and Homogeneous Catalytic Oxidation by Derek H. R. Barton, Donald T. Sawyer (auth.), Derek H. R. Barton, Arthur E. Martell, Donald T. Sawyer (eds.)
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