By Jonathan W. Steed
ISBN-10: 0470512342
ISBN-13: 9780470512340
Supramolecular chemistry is ‘chemistry past the molecule’ - the chemistry of molecular assemblies and intermolecular bonds. it really is one among today’s quickest becoming disciplines, crossing a variety of topics from organic chemistry to fabrics technological know-how; and from synthesis to spectroscopy.
Supramolecular Chemistry is an up to date, built-in textbook that tells the newcomer to the sphere every little thing they should comprehend to start. Assuming little within the means of earlier wisdom, the e-book covers the thoughts in the back of the topic, its breadth, purposes and the most recent modern pondering within the region. additionally it is insurance of the extra very important experimental and instrumental recommendations wanted by way of supramolecular chemists.
The publication has been completely up-to-date for this moment variation. as well as the strengths of the highly regarded first version, this complete new edition expands assurance right into a vast diversity of rising components. transparent reasons of either basic and nascent ideas are supplemented by way of updated assurance of intriguing rising tendencies within the literature. a variety of examples and difficulties are incorporated during the booklet. A method of “key references” permits swift entry to the secondary literature, and naturally entire fundamental literature citations are supplied. a range of the subjects lined is indexed below.
Cation, anion, ion-pair and molecular host-guest chemistry Crystal engineering Topological entanglement Clathrates Self-assembly Molecular units Dendrimers Supramolecular polymers Microfabrication Nanoparticles Chemical emergence
Metal-organic frameworks Gels Ionic drinks Supramolecular catalysis Molecular electronics Polymorphism fuel sorption Anion-pinteractions Nanochemistry
Supramolecular Chemistry is a needs to for either scholars new to the sphere and for knowledgeable researchers eager to discover the origins and wider context in their work.
Review:
"At slightly below one thousand pages, the second one variation of Steed and Atwood's Supramolecular Chemistry is the main finished assessment of the realm on hand in textbook form...highly recommended."
Chemistry global, August 2009
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Extra info for Supramolecular Chemistry
Sample text
4). 16 The enthalpic term arises from the fact that macrocyclic hosts are frequently less strongly solvated than their acyclic analogues. This is because they simply present less solvent-accessible surface area. As a result there are fewer solvent–ligand bonds to break than in the extended, acyclic case. Entropically, macrocycles are less conformationally flexible and so lose fewer degrees of freedom upon complexation. In general, the relative importance of the entropic and enthaplic terms varies according to the system studied although the enthalpy is frequently dominant as a result of additional factors such as lone pair repulsions.
8). 8 Ring size dependence of the stabilisation offered by the chelate effect. Cooperativity and the Chelate Effect 19 stable by far because they contain the least amount of ring strain, particularly for larger cations. g. chelating acetate) are highly strained, while as the chelate rings size increases the statistical likelihood of two donor atoms pointing directly at the metal becomes increasingly less probable, resulting in an unfavourable entropy. The strain energy in the chelate ring is dependent on the size of the metal cation, however.
E. a chemical entity comprising a metal of charge mϩ and a ligand, L. The square brackets are useful because they always denote the ligands directly bound to the metal so, for example, [Co(1,2-diaminoethane) 2Cl2]Br contains two Cl– ligands bound to Co(III) with a bromide counter anion balancing the overall charge, whereas [Co(1,2-diaminoethane)2ClBr]Cl contains both Co–Cl and Co–Br bonds and a chloride counter anion. 3 Binding constants for a range of complexation processes. g. binding of two Naϩ ions by dibenzo[30]crown-10).
Supramolecular Chemistry by Jonathan W. Steed
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