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Download e-book for iPad: Quantum Chemistry by Donald Allan McQuarrie

By Donald Allan McQuarrie

ISBN-10: 1891389505

ISBN-13: 9781891389504

After twenty-four years in print, Don McQuarrie has now up-to-date his landmark "Quantum Chemistry". probably the largest switch within the years because the first version is the proliferation of computational chemistry courses that calculate molecular homes. McQuarrie has offered step by step SCF calculations of a helium atom in bankruptcy nine and a hydrogen molecule in bankruptcy 10, as well as together with a complete bankruptcy at the Hartree-Fock strategy and post-Hartree-Fock tools for the calculation of molecular homes. The ebook additionally makes use of difficulties to inspire using a useful nationwide Institute of technology and know-how (NIST) site that lists experimental information and the result of numerous ab initio calculations for hundreds of thousands of molecules.

Editorial Reviews
Review
This textual content is a cut price in additional methods than one. --Journal of the yank Chemical Society

The robust issues of the publication are what one may anticipate from McQuarrie: very transparent mathematical derivations and perfect difficulties. --David Case, UC Davis
About the Author
As the writer of landmark chemistry books and textbooks, Donald McQuarrie's identify is synonymous with excellence in chemical schooling. From his vintage textual content on Statistical Mechanics to his contemporary quantum-first journey de strength on actual Chemistry, McQuarrie's top promoting textbooks are hugely acclaimed through the chemistry group. McQuarrie obtained his PhD from the collage of Oregon, and is Professor Emeritus from the dep. of Chemistry on the college of California, Davis. He makes his domestic on the Sea Ranch in California together with his spouse Carole, the place he maintains to jot down.

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Extra resources for Quantum Chemistry

Sample text

222 Plot these data to obtain a straight line, and calculate h from the slope of the line and the work function

The uncertainty principle led to an awkward result. It turns out thatthe Bohr theory is inconsistent with the uncertainty principle. Fortunately, a new, more general quantum theory was soon presented that is consistent with the uncertainty principle. We will see that this theory is applicable to all atoms and molecules and forms the basis for our understanding of atomic and molecular stmcture. This theory was formulated by the Austrian physicist Erwin Schrodinger and will be discussed in Chapter 3.

1- 23 . What is the wavelength and frequency of electromagnetic radiation having an energy of I rydberg (a rydberg is equal to 109 680 cm- 1). Convert l rydberg to electron volts and to kilojoules/mole (kJ ·mol- 1). 1-24. J 4) to calculate the wavelengths of the first three lines of the Lyman series. 1- 25. 03 x 10-1 m. Find the original energy level of the electron. 1- 26. 2 nm. It then gives off a photon that has a wavelength of 486 nm. What is the final state of the hydrogen atom? 1- 2 7. 0 nm and 1876 nm.

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Quantum Chemistry by Donald Allan McQuarrie


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