By Robert M. Fitch
ISBN-10: 0122577450
ISBN-13: 9780122577451
This quantity is constructed from many of the papers offered at a symposium held in Miami seashore in the course of the nationwide assembly of the yank Chemical Society in September, 1978. In a feeling, it's a sequel to the 1st ACS symposium hung on this subject and released less than the name "Polymer Colloids" in 1971 by way of Plenum Press. That quantity contained 12 papers, while "Polymer Colloids II" includes 33, a sign of the value of the expansion of the sector in lower than a decade. elevated sophistication most likely most sensible characterizes the alterations that have taken position, specifically within the realm of instru mentation. Ten years in the past ideas corresponding to quasielastic mild scattering, X-ray photoelectron spectroscopy (XPS - often referred to as ESCA), ion scattering spectroscopy (ISS), ultrasonic absorption spectroscopy and hydrodynamic exclusion chromatography (REC) have been unavailable to the polymer colloid chemist. contemporary advances in all of those equipment are defined during this quantity. even though the publication offers basically with "synthetic latexes" or "emulsion polymers" as colloids, there are many papers which care for their synthesis: particle nucleation in emulsion polymer ization, the synthesis of emulsifier-free polymer colloids utilizing novel reagents, molecular weight distributions derived from the kinetics of emulsion polymerization, and anionically polymerized non-aqueous polymer colloids. The kinetics and thermodynamics of the swelling of latex debris through monomers is additionally handled the following.
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39, Pergamon Press, Oxford. 13. , Aoyagi, T. and Zuikov, A. (1984). Angew. Makromol. Chem. 1231124, 261. 14. W. G. (1948). The Theory of the Stability of Lyophobic Colloids, Elsevier, Amsterdam, 15. R. (1980). M. Fitch ed), p. 209, Plenum Press, New York. 16. SiJtterlin, N. (1980). M. Fitch ed), p. 583, Plenum Press, New York. 17. V. H. (1948). J. Chem. Phys. 16, 592. 18. P. (1968). Ind. Eng. , Sept. 20, p. 20. 19. Gerrens, H. (1959). Fortsch. Hochpolym. Forsch. 1,234. 20. , Candau, F. M. (1989).
13 for 2-EHA, led Harkins and subsequently Smith and Ewart [17] to develop their famous theory of particle formation based upon radical capture by surfactant micelles. Subsequently Roe [18] showed that the same equations could be derived without invoking micelles, allowing for the possibility that homogeneous nucleation occurs, at least until j becomes large enough so that oligoradicals are irreversibly absorbed by micelles. The basis of their theories is that particle formation stops when the interfacial area (polymer/water) stabilized by the surfactant equals the area which can be covered by the amount of surfactant added, asS, where as is the area stabilized per surfactant molecule and S is the total number of surfactant CHAPTER 2 EMULSION POLYMERIZATION 23 molecules in the system.
Br. Polym. J. 5, 467. 3. K. and Ugelstad, J. (1978). J. Polym. , Polym. Chem. Ed. 16, 1953. K. and Ugelstad, J (1979). J. Polym. Sci. Polym. Chem. Ed. K. and Ugelstad, J (1979). J. Polym. Sci. Polym. Chem. Ed. 17, 3047 6. K. and Ugelstad, J (1979). J. Polym. Sci. Polym. Chem. Ed. 17, 3069 7. K. (1992). S. Daniels, D. S. E1-Aasser eds), ACS Symposium Series 492, pp. , American Chemical Society, Washington, DC. M. S. (1976). J. Polym. , Polym. Chem. Ed. 14, 2089. 9. M. H. (1973). M. Fitch ed), p.
Polymer Colloids by Robert M. Fitch
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