By Barus C.
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Extra resources for Pinhole Probe Measurements with Massive Cylindrical Air Columns
Sample text
In first-order phase transitions, the heterophase fluctuation (the nucleus of the s phase appearing in the a phase, which is at equilibrium at a given temperature) increases the free energy of the system due to the difference between the densities of the free energies of the two phases, ~, and the interphase energy. When electrons cross from the conduction band of the a phase to the heterophase fluctuation level and become localized at this level, the electron energy is reduced by the value of the activation energy of this level, u.
The Debye length is two orders of magnitude higher than the correlation length. 2] it was shown rigorously that when 2K « 2D, the correlation energy can be neglected as compared with the screening energy, which, in turn, makes it possible to neglect the correlation energy in the expression for the free energy. Naturally, at high concentrations, when 2D < 2K' this approximation is unsuitable. The condition 2D < 2K' however, corresponds to the limiting carrier concentration compatible with the existence of ferroelectricity, because then the Debye screening length is comparable with the length of the unit cell.
Formation of excited associates was discovered in a number of other investigations as well. 24] observed for the first time the effect of increase in the melting temperature of the anthracene photoisomer under the effect of electron excitations. They suggested that the appearance of excitations and the formation of excited associates increases the energy of the crystal lattice and, hence, the melting temperature of the crystals. 24], the shift in the melting point of anthracene and its derivatives depends on the intensity of the "intrinsic" illumination and may be as large as tens of degrees.
Pinhole Probe Measurements with Massive Cylindrical Air Columns by Barus C.
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