By Ronald F. Probstein
ISBN-10: 0409900893
ISBN-13: 9780409900897
''Physicochemical Hydrodynamics'' bargains with fluid movement results on actual, chemical and biochemical strategy and their speak. it's the first textual content to teach that PCH types a wel-connected physique of research with functions in lots of components of technology and know-how. the basics are offered with emphasis on rational conception and its outcomes as a way to exhibit the underlying team spirit of PCH, within which different phenomena could be describes in bodily and mathematically related methods
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Example text
The molar concentration is to be interpreted in the same context. In the energy equation, sometimes referred to as the beat conduction equation in the form written, heat flux due to interdiffusion and due to viscous dissipation have been neglected as small. Heat sources are also absent. If the problem is an electrochemical one, there is still an additional equation to define the potential distribution given by Eq. 9). This equation will introduce a dimensionless similarity parameter characterizing the potential drop.
C. Give a criterion to measure the effect of diffusive forces with respect to electrical forces. Is diffusion important? d. Estimate the particle velocity at the collector surface. Assuming the particles start from rest at the source, estimate their time to traverse the gap. 1 Equations of Change Isothermal Here we set out the equations of conservation of mass and momentum for a viscous Newtonian fluid of uniform and homogeneous composition. These two equations together with the appropriate boundary conditions are sufficient to describe the changes in velocity with respect to position and time for a viscous, isothermal flow of a uniform and homogeneous fluid.
If the rate limiting step is either steps one or three, which involves the introduction or removal of reactants, then the reaction is said to be diffusion controlled, with the rate governed by the mass transport relations previously set out. On the other hand, if step two, involving the chemical, physical, or biological transformation, is the slow step, then the rate is determined by the kinetics of the given process. As noted, within this step there may in turn be a distinction between diffusion and chemical, physical, or biochemical rates.
Physicochemical Hydrodynamics. An Introduction by Ronald F. Probstein
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