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1948, 31, 415-419. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1997. O. ch005 2 A significant enhancement of the tetramethylpyrazine (TMP) formation at high pressure was observed in the 3-hydroxy-2-butanone/ammoniumacetate model system. 82 ml/mole. A mechanism was proposed to elucidate the formation of TMP in a weak acidic condition and high hydrostatic pressure. Solvents such as PG, glycerol, methanol, ethanol, propanol, and butanol were found to enhance the TMP formation.

10) Table n . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1997. 4. LU ET AL. Maillard Browning Kinetics During Microwave Heating 43 Kinetics studies: The kinetic studies followed the procedures used by Peterson et al. (JO). D. 5%, and 5% added water contents for both the glycine-xylose and glycine-proline-xylose systems followed a similar pattern. Figures 1 and 2 represented the Maillard browning kinetics of these two systems in propylene glycol with 5% added water. From all of the plots, an induction period was observed under every reaction condition and shortened as the reaction temperature increased.

45 mg/ml. These results showed that high pressure could enhance TMP formation. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1997. 5. HUANG ET AL. 55 Kinetics of Tetramethylpyrazine Formation No TMP was detected in the oxalate system due to the low solubility of ammonium oxalate. A significant pressure effect of TMP formation was observed in the 3hydroxy-2-butanone/ammonium acetate system. 29 mg/ml respectively. 05 mg/ml. 8 folds under 2,000 kg/cm for the sample pressurized at 22 °C for 24 hours.

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