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13). Methanol ergibt bei der Oxydation nicht Kohlendioxid, sonclern Carbonat. B. Kalilauge, kontinuierlich zugefiihrt und die entstehende Kaliumcarbonat-L6sung st~indig abgeffihrt werden. Man kann den Elektrolyten regenerieren; daffir sind mehrere Verfahren denkbar; ein praktisch anwendbares Verfahren ist noch nicht bekannt geworden. ~CO3--+6H20+ 6e" ~ "--~60H Anode Elektrolyt Kothode Abb. 13. Methanol-Zelle mit alkalischem ]~lektrolyten Auch andere Alkohole kSnnen Ms Brennstoff verwendet werden; die Oxydation verIAuft jedoch nur bei Methanol vollst~indig bis zum Carbonat.
44. , A. Kahli~g u. G. Sandstede : Vortrag: Comit6 International de Thermodynamique et de Cin6tique Electrochimiques (CITCE). Zusammenfassung: Electrochimica Acta 9, X X X (1954). Ver6ffentlichung in Vorbereitung. 45. Niedrach, L. : Electrochemical Technology 3, 270 (1955). 45. Balaceanu, J. : Comptes rendus du 4e Congr~s National du P6trole 1, 37 (1960). 47. Grubb, W. , u. L. W. Niedrach: J. Electrochem. Soc. 110, 1086 (1963). 48. Osa~n, H. , A. J. Hartnev u. F. Malaspina: Nature 200, 256 (1963).
A) Der S~turefehler . . . . . . . . . b) Der Alkalifehler . . . . . . . . . 3. Ionenspezitische Glaselektroden . . . . . . 4. Praktische Grundlagen . . . . . . . . a) Allgemeines . . . . . . . . . . b) Messung yon Ionenaktivitgten . . . . . c) Genauigkeit . . . . . . . . . . 5. Anwendungen . . . . . . . . . . Literatur . . . . . . . . . . . . . . . . . . . . . . . . . . , .... . . . .
Elektrochemie
by George
4.5