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1963) Biochim. Biophys. Acta 67, 104–137. E. S. (1965) J. Biol. Chem. 240, 863-869. S. (1942) J. Biol. Chem. 146, 85–93. Fischer, E. (1894) Ber. Dtsch. Chem. Ges. 27, 2985-2993. S. (1932) Biochem. J. 26,1406-1421. Henri, V. (1902) R. Hebd, Seances Acad. Sci. 135, 916–919. J. (1952) J. Biol. Chem. 199, 357–364. Hultin, E. (1967) Acta Chem. Scand. 21, 1575–1590. Inouye, A. S. (1967) Biochemistry 6, 1765–1777. Johanson, G. & Lumry, R. (1961) C. R. Trav. Lab. Carlsberg 32, 185–214. Lineweaver, H. & Burk, D.

In contrast, intermediates, whose bonds are fully formed, occupy the troughs in the diagram. A simple way of deriving the rate law of reaction is to consider that the transition state and the ground state are in thermodynamic equilibrium, so that the concentration of the transition state may be calculated from the difference in their energies. The overall reaction rate is then obtained by multiplying the concentration of the transition state by the rate constant for its decomposition. Transition-state theory can also be expressed in thermodynamic terms (Panchenkov & Lebedev, 1976; Moore & Pearson, 1982; Atkins & de Paula, 2002).

J. 26,1406-1421. Henri, V. (1902) R. Hebd, Seances Acad. Sci. 135, 916–919. J. (1952) J. Biol. Chem. 199, 357–364. Hultin, E. (1967) Acta Chem. Scand. 21, 1575–1590. Inouye, A. S. (1967) Biochemistry 6, 1765–1777. Johanson, G. & Lumry, R. (1961) C. R. Trav. Lab. Carlsberg 32, 185–214. Lineweaver, H. & Burk, D. (1934) J. Am. Chem. Soc. 56, 658–666. Michaelis, L. L. (1913) Biochem. Z. 49, 333–369. O’Sullivan, C. W. (1890) J. Chem. Soc. Trans. 57, 834–931. J. & Prvan, T. (1996) J. Theor. Biol. 178, 239–254.

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Electrical Conductivity and Oxygen Nonstoichiometry of La0.2Sr0.8Fe0.55Ti0.45O3-d by Chan Young Park and Allan J. Jacobson


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