By Ana C. F. Ribeiro, Cecilia I. A. V. Santos, Gennady E. Zaikov
ISBN-10: 177188259X
ISBN-13: 9781771882590
ISBN-10: 1771882603
ISBN-13: 9781771882606
"This new quantity offers modern study within the speedily altering and evolving box of chemical fabrics characterization and amendment. the subjects within the ebook replicate the variety of study advances in actual chemistry and electrochemistry, targeting the education, characterization, and functions of polymers and high-density fabrics. additionally coated are quite a few production techniques. Read more...
summary: "This new quantity offers modern learn within the swiftly altering and evolving box of chemical fabrics characterization and amendment. the subjects within the publication replicate the variety of study advances in actual chemistry and electrochemistry, targeting the guidance, characterization, and purposes of polymers and high-density fabrics. additionally coated are a variety of production recommendations. concentrating on the main technologically very important fabrics being applied and built through scientists and engineers, the ebook may help to fill the distance among conception and perform in undefined. This entire anthology covers a number of the significant issues of actual chemistry and electrochemistry, addressing a few of the significant concerns, from thought to expertise to implementation. it truly is a massive reference booklet that offers new examine and updates on various actual chemistry and electrochemistry makes use of via case reports and helping applied sciences, and it additionally explains the conceptual pondering at the back of present makes use of and power makes use of now not but applied. overseas specialists with numerous years of expertise lend this quantity credibility."
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Additional info for Chemical analysis: modern materials evaluation and testing methods
Example text
BThecation–anion distance is optimized without considering the presence of the solvent molecules. cThecation–water–anion distance is optimized considering this system (cation + anion + 5H2O) in the gas phase. dThecation–water–anion distance is optimized considering this system (cation + anion + 5H2O) in the presence of the water solvent, simulated by considering the solute inserted in a solvent cavity. eThese values represent the distance between the centers of cation and anion without water. fThese values represent the distance between the centers of cation and anion with one water moleculebetween them.
5 Conclusion...................................................................................... 50 Acknowledgments.................................................................................... 50 Keywords................................................................................................. 50 References................................................................................................ 50 18 Chemical Anaylsis: Modern Materials Evaluation and Testing Methods ABSTRACT A review on the importance of the estimated numerical values present in the literature for the mean distance of closest approach of ions, a, of electrolytes in aqueous solutions, determined from activity and diffusion coefficients and estimated by using different theoretical approaches, is presented and discussed.
5×10−10 m, respectively) in which this is not verified, as shown by values of a which are less than the sum of the radii of the “bare” ions, in apparent contradiction to the physical meaning of this parameter. In fact, it is observed that in those cases, the choice of a alters substantially the calculations of their D from Eq. 4). This is not surprising if factors likethe formation of complex ions and the variety of ion pairs eventually formed,23 and the change with concentration of parameters such as viscosity, dielectric constant, hydration, and hydrolysis of ions,51–54 not considered in Onsager–Fuoss theory, are taken into account.
Chemical analysis: modern materials evaluation and testing methods by Ana C. F. Ribeiro, Cecilia I. A. V. Santos, Gennady E. Zaikov
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