By Jean Rouquerol, Visit Amazon's Françoise Rouquerol Page, search results, Learn about Author Central, Françoise Rouquerol, , Kenneth S.W. Sing
ISBN-10: 0080526012
ISBN-13: 9780080526010
ISBN-10: 0125989202
ISBN-13: 9780125989206
The declared target of this booklet is to supply an introductory overview of some of the theoretical and sensible features of adsorption via powders and porous solids with specific connection with fabrics of technological significance. the first target is to satisfy the wishes of scholars and non-specialists, who're new to floor technology or who desire to use the complex recommendations now to be had for the selection of floor quarter, pore measurement and floor characterization. moreover, a severe account is given of contemporary paintings at the adsorptive houses of activated carbons, oxides, clays and zeolites. Key beneficial properties * presents a accomplished therapy of adsorption at either the gas/solid interface and the liquid/solid interface * contains chapters facing experimental technique and the translation of adsorption facts acquired with porous oxides, carbons and zeolites * innovations seize the significance of heterogeneous catalysis, chemical engineering and the creation of pigments, cements, agrochemicals, and prescribed drugs
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Additional info for Adsorption by Powders and Porous Solids: Principles, Methodology and Applications
Example text
Overbeek J. Th. G. H. H. Ottewill, eds), Butterworths, London, p. 3. Polanyi M. (1914) Verb. Deutsch Phys. , 16, 1012. S. (1822) Ann. Chim. , 20, 141. , Hailer G. V. V. ) Elsevier, Amsterdam, p. 203. , Pisani, C. and Garrone, E. (1971) In: Adsorption-Desorption Phenomena, Academic Press, London, p. 111. K. (1932) In: The Adsorption of Gases by Solids, Disc. Faraday Society, London, p. 139. Robens E. (1994) In: Characterization of Porous Solids III (J. Rouquerol, F. W. K. Unger, eds), Elsevier, Amsterdam, p.
4. The chromatographic method . . . . . . . . . . . . . . . . 1. Introduction The major advances in the application of classical thermodynamics to gas adsorption were made many years ago. , 1973; Myers, 1987; Kadlec, 1989). The aim of this chapter is simply to introduce a selection of the most appropriate thermodynamic quantities for the processing and interpretation of adsorption isotherm and calorimetric data, which are obtained by the methods described in Chapter 3. We do not consider here the thermodynamic implications of capillary condensation, since these are dealt with in Chapter 7.
Types of Adsorption Isotherms The amount of gas adsorbed, n a, by the mass, m s, of solid is dependent on the equilibrium pressure, p, the temperature, T, and the nature of the gas-solid system. 9) where here, the standard pressure pO is equal to the saturation pressure of the adsorptive at T. 9) represent the adsorption isotherm which is the relationship between the amount adsorbed by unit mass of solid and the equilibrium pressure (or relative pressure), at a known temperature. The experimental adsorption isotherm is usually presented in graphical form.
Adsorption by Powders and Porous Solids: Principles, Methodology and Applications by Jean Rouquerol, Visit Amazon's Françoise Rouquerol Page, search results, Learn about Author Central, Françoise Rouquerol, , Kenneth S.W. Sing
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